Structures of the trisulfur oxides S3O and S3O˙+: branched rings, not open chains
Abstract
Higher-level ab initio calculations showed that the global energy minimum for both S3O and S3O˙+ is a branched, three-membered ring, not an open chain form.
* Corresponding authors
a
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail:
chmwmw@nus.edu.sg
Fax: 65 67791691
Tel: 68744320
b
Institut für Chemie, Technische Universität Berlin, Sekr. C2, Berlin, Germany
E-mail:
steudel@sulfur-research.de
Fax: 49 30 31426519
Tel: 49 30 31422707
Higher-level ab initio calculations showed that the global energy minimum for both S3O and S3O˙+ is a branched, three-membered ring, not an open chain form.
M. W. Wong and R. Steudel, Chem. Commun., 2005, 3712 DOI: 10.1039/B507235B
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