Issue 31, 2005
From the journal:

Chemical Communications

Diastereoselective Ni(0)-catalyzed carbocyclization to chiral vinylic sulfoxide

Naoyoshi Maezaki,a   Hiroaki Sawamoto,a   Hiroyuki Ishiharaa  and  Tetsuaki Tanaka*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka, Japan
E-mail: t-tanaka@phs.osaka-u.ac.jp
Fax: +81-6-6879-8210
Tel: +81-0-6879-8214

Abstract

Diastereoselective Ni(0)-catalyzed carbocyclization of enone to chiral vinylic sulfoxide has been accomplished, wherein two stereogenic centers were constructed simultaneously to give cis- and trans-disubstituted cyclopentanes from (E)- and (Z)-vinylic sulfoxides, respectively.

Graphical abstract: Diastereoselective Ni(0)-catalyzed carbocyclization to chiral vinylic sulfoxide

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B506375B
Article type
Communication
Submitted
06 May 2005
Accepted
10 Jun 2005
First published
11 Jul 2005

Chem. Commun., 2005, 3992-3994

Permissions

Request permissions

Diastereoselective Ni(0)-catalyzed carbocyclization to chiral vinylic sulfoxide

N. Maezaki, H. Sawamoto, H. Ishihara and T. Tanaka, Chem. Commun., 2005, 3992 DOI: 10.1039/B506375B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements