Issue 28, 2005
From the journal:

Chemical Communications

CuI-catalyzed intramolecular O-vinylation of carbonyl compounds†

Yewen Fanga  and  Chaozhong Li*a  

* Corresponding authors

a Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, P. R. China
E-mail: clig@mail.sioc.ac.cn
Fax: +86-21-6416-6128

Abstract

The first copper-catalyzed intramolecular O-vinylation of carbonyl compounds with vinyl bromides was reported, among which the efficient formation of 5-, 6- and even 7-membered cyclic alkenyl ethers was achieved with β-ketoesters as nucleophiles.

Graphical abstract: CuI-catalyzed intramolecular O-vinylation of carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/B505006E
Article type
Communication
Submitted
11 Apr 2005
Accepted
11 May 2005
First published
01 Jun 2005

Chem. Commun., 2005, 3574-3576

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CuI-catalyzed intramolecular O-vinylation of carbonyl compounds

Y. Fang and C. Li, Chem. Commun., 2005, 3574 DOI: 10.1039/B505006E

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