Issue 25, 2005
From the journal:

Chemical Communications

A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes†

Sylvestre Bonnet,a   Jean-Paul Collin*a  and  Jean-Pierre Sauvagea  

* Corresponding authors

a Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, 67000 Strasbourg Cedex, France
E-mail: jpcollin@chimie.u-strasbg.fr

Abstract

A Ru(terpy)(phen) motif has been inscribed in a 39-membered ring by functionalizing the ligands and subsequently performing a cyclization reaction on the complex; by visible light irradiation, a dramatic geometrical changeover of the cyclic complex takes place which can be reversed thermally.

Graphical abstract: A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

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Article information

DOI
https://doi.org/10.1039/B503411F
Article type
Communication
Submitted
09 Mar 2005
Accepted
27 Apr 2005
First published
24 May 2005

Chem. Commun., 2005, 3195-3197

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A Ru(terpy)(phen)-incorporating ring and its light-induced geometrical changes

S. Bonnet, J. Collin and J. Sauvage, Chem. Commun., 2005, 3195 DOI: 10.1039/B503411F

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