Issue 25, 2005
From the journal:

Chemical Communications

Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides†

Ryo Shintani,a   Takahiro Kimuraa  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: thayashi@kuchem.kyoto-u.ac.jp
Fax: +81-75-753-3988
Tel: +81-75-753-3983

Abstract

Rhodium/chiral diene (S,S)-3b complex has been found to effectively catalyze the 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides, furnishing useful β-chiral Weinreb amides in high enantioselectivity.

Graphical abstract: Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides

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Article information

DOI
https://doi.org/10.1039/B502921J
Article type
Communication
Submitted
28 Feb 2005
Accepted
22 Apr 2005
First published
18 May 2005

Chem. Commun., 2005, 3213-3214

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Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides

R. Shintani, T. Kimura and T. Hayashi, Chem. Commun., 2005, 3213 DOI: 10.1039/B502921J

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