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Issue 25, 2005
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Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides

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Abstract

Rhodium/chiral diene (S,S)-3b complex has been found to effectively catalyze the 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides, furnishing useful β-chiral Weinreb amides in high enantioselectivity.

Graphical abstract: Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides

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Article information


Submitted
28 Feb 2005
Accepted
22 Apr 2005
First published
18 May 2005

Chem. Commun., 2005, 3213-3214
Article type
Communication

Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated Weinreb amides

R. Shintani, T. Kimura and T. Hayashi, Chem. Commun., 2005, 3213
DOI: 10.1039/B502921J

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