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Issue 31, 2005
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Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

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Abstract

Primary and secondary kinetic and equilibrium isotope effects are calculated with density-functional methods for the dianionic methanolysis of the native (unsubstituted) and thio-substituted ethylene phosphates.

Graphical abstract: Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

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Article information


Submitted
22 Feb 2005
Accepted
23 May 2005
First published
06 Jul 2005

Chem. Commun., 2005, 3909-3911
Article type
Communication

Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

Y. Liu, X. Lopez and D. M. York, Chem. Commun., 2005, 3909
DOI: 10.1039/B502568K

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