Issue 31, 2005
From the journal:

Chemical Communications

Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

Yun Liu,a   Xabier Lopezb  and  Darrin M. York*a  

* Corresponding authors

a Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, USA
E-mail: york@chem.umn.edu
Fax: 612 626 2006
Tel: 612 624 8042

b Kimika Fakultatea, Euskal Herriko Unibertsitatea, P.K. 1072, Donostia, Euskadi, Spain

Abstract

Primary and secondary kinetic and equilibrium isotope effects are calculated with density-functional methods for the dianionic methanolysis of the native (unsubstituted) and thio-substituted ethylene phosphates.

Graphical abstract: Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

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Article information

DOI
https://doi.org/10.1039/B502568K
Article type
Communication
Submitted
22 Feb 2005
Accepted
23 May 2005
First published
06 Jul 2005

Chem. Commun., 2005, 3909-3911

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Kinetic isotope effects on thio-substituted biological phosphoryl transfer reactions from density-functional theory

Y. Liu, X. Lopez and D. M. York, Chem. Commun., 2005, 3909 DOI: 10.1039/B502568K

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