Issue 23, 2005
From the journal:

Chemical Communications

Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

Hisahiro Hagiwara,*a   Yoshitaka Sugawara,a   Takashi Hoshib  and  Toshio Suzukib  

* Corresponding authors

a Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata, Japan
E-mail: hagiwara@gs.niigata-u.ac.jp
Fax: +81-25-262-7368
Tel: +81-25-262-7368

b Faculty of Engineering, Niigata University, 8050, 2-Nocho, Ikarashi, Japan

Abstract

Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim]PF6, was highly efficient in the promotion of the Mizoroki–Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h−1), respectively.

Graphical abstract: Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

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Article information

DOI
https://doi.org/10.1039/B502528A
Article type
Communication
Submitted
22 Feb 2005
Accepted
18 Apr 2005
First published
05 May 2005

Chem. Commun., 2005, 2942-2944

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Sustainable Mizoroki–Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

H. Hagiwara, Y. Sugawara, T. Hoshi and T. Suzuki, Chem. Commun., 2005, 2942 DOI: 10.1039/B502528A

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