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Issue 21, 2005
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Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability

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Abstract

Three novel Mn, Co, and Zn MOFs containing large tetrahedral cages have been prepared and are stable up to 400 °C; X-ray diffraction revealed the frameworks are isostructural having a diamondoid structure of “hourglass” subunits connected by triangular carboxylate ligands.

Graphical abstract: Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability

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Publication details

The article was received on 10 Feb 2005, accepted on 05 Apr 2005 and first published on 15 Apr 2005


Article type: Communication
DOI: 10.1039/B502007G
Chem. Commun., 2005, 2663-2665

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    Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability

    D. Sun, S. Ma, Y. Ke, T. M. Petersen and H. Zhou, Chem. Commun., 2005, 2663
    DOI: 10.1039/B502007G

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