New titanium and zirconium complexes with M–NH2 bonds formed by facile deprotonation of H3N·B(C6F5)3
Abstract
Facile deprotonation of H3N·B(C6F5)3 with [M(NMe2)4] (M = Zr or Ti) yields the novel amidoborate complexes [Zr(NMe2)3{NH2B(C6F5)3}(HNMe2)] and [Ti(NMe2)3{NH2B(C6F5)3}].