Issue 13, 2005
From the journal:

Chemical Communications

Photocatalytic formation of a carbamate through ethanol-assisted carbonylation of p-nitrotoluene†

Andrea Maldotti,*a   Rossano Amadelli,a   Luca Samiolo,a   Alessandra Molinari,a   Andrea Penoni,b   Stefano Tollarib  and  Sergio Ceninic  

* Corresponding authors

a Dipartimento di Chimica, Sezione ISOF –CNR, Università di Ferrara, Via L. Borsari 46, Ferrara, Italy
E-mail: mla@dns.unife.it

b Dipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, Via Valleggio 11, Como, Italy

c Dipartimento di Chimica Inorganica Metallorganica e Analitica, I.S.T.M.- C.N.R., Università di Milano, Via G. Venezian 21, Milano, Italy

Abstract

The nitroarene p-nitrotoluene is converted with a selectivity higher than 85% to the corresponding carbamate at room temperature and atmospheric pressure, using photoexcited particles of TiO2 as catalyst and EtOH as carbonylating species.

Graphical abstract: Photocatalytic formation of a carbamate through ethanol-assisted carbonylation of p-nitrotoluene

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Article information

DOI
https://doi.org/10.1039/B418571D
Article type
Communication
Submitted
10 Dec 2004
Accepted
13 Jan 2005
First published
07 Feb 2005

Chem. Commun., 2005, 1749-1751

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Photocatalytic formation of a carbamate through ethanol-assisted carbonylation of p-nitrotoluene

A. Maldotti, R. Amadelli, L. Samiolo, A. Molinari, A. Penoni, S. Tollari and S. Cenini, Chem. Commun., 2005, 1749 DOI: 10.1039/B418571D

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