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Issue 14, 2005
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Regioselective allylgallation of terminal alkynes

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Abstract

The reactions of terminal alkynes with allylgallium reagents generated in situ from gallium and allyl bromides gave the corresponding 1,4-dienes in good yield via Markovnikov addition in THF at 70 °C.

Graphical abstract: Regioselective allylgallation of terminal alkynes

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Article information


Submitted
30 Nov 2004
Accepted
27 Jan 2005
First published
09 Feb 2005

Chem. Commun., 2005, 1874-1876
Article type
Communication

Regioselective allylgallation of terminal alkynes

P. H. Lee, Y. Heo, D. Seomoon, S. Kim and K. Lee, Chem. Commun., 2005, 1874
DOI: 10.1039/B417975G

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