Issue 16, 2005
From the journal:

Chemical Communications

Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal–organic framework

Jarrod F. Eubank,a   Rosa D. Walsha  and  Mohamed Eddaoudi*a  

* Corresponding authors

a Department of Chemistry, University of South Florida, 4202 E. Fowler Ave. (SCA 400), Tampa, USA
E-mail: eddaoudi@cas.usf.edu

Abstract

A neutral, non-interpenetrated porous metal–organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF = N,N′-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO2)2, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.

Graphical abstract: Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal–organic framework

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Article information

DOI
https://doi.org/10.1039/B417013J
Article type
Communication
Submitted
09 Nov 2004
Accepted
07 Feb 2005
First published
03 Mar 2005

Chem. Commun., 2005, 2095-2097

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Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal–organic framework

J. F. Eubank, R. D. Walsh and M. Eddaoudi, Chem. Commun., 2005, 2095 DOI: 10.1039/B417013J

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