Issue 10, 2005
From the journal:

Chemical Communications

Asymmetric alkylation of dimethoxyphosphoryl-N-[1-(S)-α-methylbenzyl]acetamide enolates. Synthesis of both stereoisomers from the same source of chirality by changing the equivalents of LDA†

Mario Ordóñez,*a   Eugenio Hernández-Fernández,a   Janet Xahuentitlaa  and  Carlos Cativielab  

* Corresponding authors

a Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, 62210 Cuernavaca, Mor., Mexico
E-mail: palacios@buzon.uaem.mx
Fax: 527773297997
Tel: 527773297997

b Department of Organic Chemistry, ICMA, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain
Fax: 34976761210
Tel: 34976761210

Abstract

A new methodology has been developed for the synthesis of both stereoisomers from a single chiral source.

Graphical abstract: Asymmetric alkylation of dimethoxyphosphoryl-N-[1-(S)-α-methylbenzyl]acetamide enolates. Synthesis of both stereoisomers from the same source of chirality by changing the equivalents of LDA

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Article information

DOI
https://doi.org/10.1039/B416616G
Article type
Communication
Submitted
02 Nov 2004
Accepted
01 Dec 2004
First published
18 Jan 2005

Chem. Commun., 2005, 1336-1338

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Asymmetric alkylation of dimethoxyphosphoryl-N-[1-(S)-α-methylbenzyl]acetamide enolates. Synthesis of both stereoisomers from the same source of chirality by changing the equivalents of LDA

M. Ordóñez, E. Hernández-Fernández, J. Xahuentitla and C. Cativiela, Chem. Commun., 2005, 1336 DOI: 10.1039/B416616G

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