Issue 9, 2005
From the journal:

Chemical Communications

First successful application of diphosphite ligands in the asymmetric hydroformylation of dihydrofurans

Montserrat Diéguez,*a   Oscar Pamiesa  and  Carmen Claver*a  

* Corresponding authors

a Departament de Química Física i Inorgànica. Universitat Rovira i Virgili. C/Marcel·li Domingo, s/n. 43007 Tarragona, Spain
E-mail: montserrat.dieguez@urv.net

Abstract

Good enantioselectivities and excellent regioselectivities are achieved in the Rh-catalyzed asymmetric hydroformylation of 2,5- and 2,3-dihydrofuran using diphosphite ligands; whereby the backbone of the ligand is crucial to suppressing isomerization and obtaining high ee's.

Graphical abstract: First successful application of diphosphite ligands in the asymmetric hydroformylation of dihydrofurans

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Article information

DOI
https://doi.org/10.1039/B416514D
Article type
Communication
Submitted
28 Oct 2004
Accepted
10 Dec 2004
First published
19 Jan 2005

Chem. Commun., 2005, 1221-1223

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First successful application of diphosphite ligands in the asymmetric hydroformylation of dihydrofurans

M. Diéguez, O. Pamies and C. Claver, Chem. Commun., 2005, 1221 DOI: 10.1039/B416514D

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