A high spin molecular square based on square pyramidal CoII and tetrahedral MnII centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]

Ferdi Karadas; Eric J. Schelter; Andrey V. Prosvirin; John Bacsa; Kim R. Dunbar

doi:10.1039/B415168B

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A high spin molecular square based on square pyramidal Co^II and tetrahedral Mn^II centers: [{Mn^IICl₂}₂{Co^II(triphos)(CN)₂}₂]†

Ferdi Karadas,^a Eric J. Schelter,^a Andrey V. Prosvirin,^a John Bacsa^a and Kim R. Dunbar*^a

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^a Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012, USA
E-mail: dunbar@mail.chem.tamu.edu
Fax: 979 845 7177
Tel: 979 845 5235

Abstract

A high spin molecular square of square pyramidal Co^II and tetrahedral Mn^II corners exhibiting an overall S = 4 ground state has been crystallized and its magnetic properties investigated.

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Article information

DOI: https://doi.org/10.1039/B415168B
Article type: Communication
Submitted: 30 Sep 2004
Accepted: 22 Dec 2004
First published: 02 Feb 2005

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Chem. Commun., 2005, 1414-1416

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A high spin molecular square based on square pyramidal Co^II and tetrahedral Mn^II centers: [{Mn^IICl₂}₂{Co^II(triphos)(CN)₂}₂]

F. Karadas, E. J. Schelter, A. V. Prosvirin, J. Bacsa and K. R. Dunbar, Chem. Commun., 2005, 1414 DOI: 10.1039/B415168B

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Chemical Communications