Issue 2, 2005

A heme-like, water-soluble iron(ii) porphyrin: thermal and photoinduced properties, evidence for sitting-atop structure

Abstract

Water-soluble ferrous porphyrin (FeIITPPS) was prepared by complexation reaction of free base porphyrin (H2TPPS) with iron(II) ions in the presence of iron(III)-trapping acetate buffer; the catalytic and photoinduced properties of this air-stable complex proved unambiguously its sitting-atop structure.

Graphical abstract: A heme-like, water-soluble iron(ii) porphyrin: thermal and photoinduced properties, evidence for sitting-atop structure

Article information

Article type
Communication
Submitted
23 Sep 2004
Accepted
14 Oct 2004
First published
23 Nov 2004

Chem. Commun., 2005, 224-226

A heme-like, water-soluble iron(II) porphyrin: thermal and photoinduced properties, evidence for sitting-atop structure

R. Huszánk and O. Horváth, Chem. Commun., 2005, 224 DOI: 10.1039/B414673E

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