Issue 5, 2005
From the journal:

Chemical Communications

Trinuclear coordinatively labile Cu(ii) complex of 4,6-O-ethylidene-β-d-glucopyranosylamine derived Schiff baseligand and its reactivity towards primary alcohols and amines†

Ajay K. Sah,a   Merii Katoa  and  Tomoaki Tanase*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara 630-8285, Japan
E-mail: tanase@cc.nara-wu.ac.jp
Fax: +81 742 203399
Tel: +81 742 203399

Abstract

A novel neutral trinuclear Cu(II) complex of a Schiff base ligand derived from D-glucose has been synthesised and structurally characterised, which exhibits excellent alcohol binding affinity and activates the C–Cl bond of chloroform in the presence of primary amine.

Graphical abstract: Trinuclear coordinatively labile Cu(ii) complex of 4,6-O-ethylidene-β-d-glucopyranosylamine derived Schiff base ligand and its reactivity towards primary alcohols and amines

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Article information

DOI
https://doi.org/10.1039/B413923B
Article type
Communication
Submitted
10 Sep 2004
Accepted
02 Nov 2004
First published
08 Dec 2004

Chem. Commun., 2005, 675-677

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Trinuclear coordinatively labile Cu(II) complex of 4,6-O-ethylidene-β-D-glucopyranosylamine derived Schiff base ligand and its reactivity towards primary alcohols and amines

A. K. Sah, M. Kato and T. Tanase, Chem. Commun., 2005, 675 DOI: 10.1039/B413923B

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