Issue 7, 2005

The first example of a liquid crystalline side-chain polymer with bent-core mesogenic units: ferroelectric switching and spontaneous achiral symmetry breaking in an achiral polymer

Abstract

A dimethylsiloxane diluted polysiloxane side chain co-polymer with non-chiral banana-shaped mesogenic units shows an optically isotropic ferroelectric switching polar smectic C phase (SmCPF) consisting of a conglomerate of homogeneously chiral domains with opposite handedness.

Graphical abstract: The first example of a liquid crystalline side-chain polymer with bent-core mesogenic units: ferroelectric switching and spontaneous achiral symmetry breaking in an achiral polymer

Article information

Article type
Communication
Submitted
07 Sep 2004
Accepted
18 Nov 2004
First published
05 Jan 2005

Chem. Commun., 2005, 871-873

The first example of a liquid crystalline side-chain polymer with bent-core mesogenic units: ferroelectric switching and spontaneous achiral symmetry breaking in an achiral polymer

C. Keith, R. A. Reddy and C. Tschierske, Chem. Commun., 2005, 871 DOI: 10.1039/B413643H

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