Issue 1, 2005
From the journal:

Chemical Communications

One-step synthesis of alkoxyamines for nitroxide-mediated radical polymerization

Robert B. Grubbs,*a   Jakub K. Wegrzyna  and  Qing Xiaa  

* Corresponding authors

a Department of Chemistry and Center for Nanomaterials Research, 6128 Burke Laboratory, Dartmouth College, Hanover, NH, USA
E-mail: Robert.B.Grubbs@Dartmouth.edu
Fax: +1 603 646 3946
Tel: +1 603 646 9096

Abstract

An alkoxyamine that is an effective initiator for the controlled polymerization of styrene and isoprene has been prepared by the reaction of 2-methyl-2-nitrosopropane with two equivalents of radicals derived from 1-bromoethylbenzene.

Graphical abstract: One-step synthesis of alkoxyamines for nitroxide-mediated radical polymerization

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Article information

DOI
https://doi.org/10.1039/B413358G
Article type
Communication
Submitted
02 Sep 2004
Accepted
04 Oct 2004
First published
29 Nov 2004

Chem. Commun., 2005, 80-82

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One-step synthesis of alkoxyamines for nitroxide-mediated radical polymerization

R. B. Grubbs, J. K. Wegrzyn and Q. Xia, Chem. Commun., 2005, 80 DOI: 10.1039/B413358G

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