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Issue 22, 2005
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Michael, Michael–aldol and Michael–Michael reactions of enolate equivalents of butane-2,3-diacetal protected glycolic acid derivatives

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Abstract

Consecutive coupling reactions of butane-2,3-diacetal protected glycolic acid derivatives with Michael acceptors and aldehydes are reported. An enantiopure sample of this building block was used to kinetically resolve a chiral Michael acceptor present as a racemic mixture of enantiomers.

Graphical abstract: Michael, Michael–aldol and Michael–Michael reactions of enolate equivalents of butane-2,3-diacetal protected glycolic acid derivatives

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Article information


Submitted
06 Sep 2005
Accepted
30 Sep 2005
First published
19 Oct 2005

Org. Biomol. Chem., 2005,3, 4095-4107
Article type
Paper

Michael, Michael–aldol and Michael–Michael reactions of enolate equivalents of butane-2,3-diacetal protected glycolic acid derivatives

S. V. Ley, D. J. Dixon, R. T. Guy, F. Rodríguez and T. D. Sheppard, Org. Biomol. Chem., 2005, 3, 4095
DOI: 10.1039/B512410G

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