Issue 7, 2005

Piperazine additions to C60—a facile approach to fullerene substitution

Abstract

A range of fullerene monoadducts can be generated via the photochemical reaction of piperazine derivatives with C60. Addend functionality can also be efficiently incorporated by transformation of the hydroxyl-substituted adduct prepared in this fashion. Reaction yields and process simplicity compete with current standard procedures for fullerene mono-functionalisation.

Graphical abstract: Piperazine additions to C60—a facile approach to fullerene substitution

Article information

Article type
Paper
Submitted
27 Aug 2004
Accepted
19 Jan 2005
First published
22 Feb 2005

Org. Biomol. Chem., 2005,3, 1209-1216

Piperazine additions to C60—a facile approach to fullerene substitution

C. P. Butts and M. D. S. Jazdzyk, Org. Biomol. Chem., 2005, 3, 1209 DOI: 10.1039/B413173H

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