Issue 9, 2005
From the journal:

New Journal of Chemistry

A calixarene–amide–tetrathiafulvaleneassembly for the electrochemical detection of anions†

Bang-Tun Zhao,a   María-Jesús Blesa,a   Nicolas Mercier,a   Franck Le Derfa  and  Marc Sallé*a  

* Corresponding authors

a Laboratoire de Chimie et Ingénierie Moléculaire des Matériaux d’Angers (CIMMA), Groupe Synthèse Organique et Matériaux Fonctionnels, UMR CNRS 6200, Université d'Angers, 2 Bd Lavoisier, F-49045 Angers, France
E-mail: marc.salle@univ-angers.fr
Fax: +33 241735405
Tel: +33 241735439

Abstract

The synthesis of a calix[4]arene derivative bearing pendant tetrathiafulvalene (TTF) units is described. Two electroactive TTF units are linked to the calix[4]arene platform through amide functions for the binding of anions. An X-ray structure of a calixarene–amide–TTF assembly existing in a cone conformation is provided. The binding ability of this receptor for H2PO4− is shown by 1H-NMR and electrochemical studies (cyclic voltammetry).

Graphical abstract: A calixarene–amide–tetrathiafulvalene assembly for the electrochemical detection of anions

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Article information

DOI
https://doi.org/10.1039/B504339E
Article type
Paper
Submitted
29 Mar 2005
Accepted
03 Jun 2005
First published
14 Jul 2005

New J. Chem., 2005,29, 1164-1167

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A calixarene–amide–tetrathiafulvalene assembly for the electrochemical detection of anions

B. Zhao, M. Blesa, N. Mercier, F. Le Derf and M. Sallé, New J. Chem., 2005, 29, 1164 DOI: 10.1039/B504339E

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