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Issue 2, 2005
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Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

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Abstract

Four new bis monodentate tectons 14 based on the diazadioxa (5)- and diazatetraoxa (6)-macrocyclic backbones bearing two pyridine units as coordinating sites have been designed and prepared. In the presence of copper diacetate, their ability to form coordination networks was demonstrated by structural studies based on X-ray diffraction methods. Both tectons 1 and 2 behave as bis monodentate units and their bridging by copper diacetate dimer behaving as a linear metallatecton leads to the formation of analogous 1D coordination networks.

Graphical abstract: Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

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Publication details

The article was received on 19 Oct 2004, accepted on 23 Nov 2004 and first published on 06 Jan 2005


Article type: Paper
DOI: 10.1039/B416145A
New J. Chem., 2005,29, 343-346

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    Molecular tectonics: design of coordinating tectons based on diazamacrocycles bearing pyridine units and formation of 1D copper coordination networks

    E. Graf, M. Wais Hosseini, J. Planeix and N. Kyritsakas, New J. Chem., 2005, 29, 343
    DOI: 10.1039/B416145A

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