Issue 13, 2005
From the journal:

Dalton Transactions

Easy hydrolysis of white phosphorus coordinated to ruthenium

Massimo Di Vaira,a   Piero Frediani,b   Stefano Seniori Costantini,a   Maurizio Peruzzinic  and  Piero Stoppioni*a  

* Corresponding authors

a Dipartimento di Chimica, Università di Firenze, via della Lastruccia n. 3, Sesto Fiorentino, Firenze, Italy
E-mail: piero.stoppioni@unifi.it

b Dipartimento di Chimica Organica “Ugo Schiff”, Università di Firenze, via della Lastruccia n. 13, Sesto Fiorentino, Firenze, Italy
E-mail: piero.frediani@unifi.it

c ICCOM CNR, Via Madonna del Piano, snc, Sesto Fiorentino, Firenze, Italy
E-mail: mperuzzini@iccom.cnr.it

Abstract

The P4 molecule bound to ruthenium as an η1-ligand in [CpRu(PPh3)2(η1-P4)]Y (Y = PF6, CF3SO3) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3, which remains coordinated to the [CpRu(PPh3)2] fragment, and oxygenated derivatives.

Graphical abstract: Easy hydrolysis of white phosphorus coordinated to ruthenium

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B504795A
Article type
Communication
Submitted
06 Apr 2005
Accepted
19 May 2005
First published
31 May 2005

Dalton Trans., 2005, 2234-2236

Permissions

Request permissions

Easy hydrolysis of white phosphorus coordinated to ruthenium

M. Di Vaira, P. Frediani, S. S. Costantini, M. Peruzzini and P. Stoppioni, Dalton Trans., 2005, 2234 DOI: 10.1039/B504795A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements