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Issue 104, 2005

Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

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Abstract

The role played by different anions (XF6 (X = P, As, Sb), BF4) on the connectivity of coordination networks formed by a combination of different silver salts and an organic tecton based on piperazine bearing two pyridine units has been studied in the crystalline phase by X-ray diffraction on single crystal. All four weakly coordinating anions lead to the formation of analogous 2-D coordination networks. For the isostructural anions XF6 (X = P, As, Sb) the crystals are isomorphous.

Graphical abstract: Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

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Publication details

The article was received on 15 Sep 2005, accepted on 02 Nov 2005 and first published on 07 Nov 2005


Article type: Paper
DOI: 10.1039/B513138N
CrystEngComm, 2005,7, 624-628

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    Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks

    D. Pocic, J. Planeix, N. Kyritsakas, A. Jouaiti and M. W. Hosseini, CrystEngComm, 2005, 7, 624
    DOI: 10.1039/B513138N

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