Issue 98, 2005
From the journal:

CrystEngComm

Polymorphs of 4′-(hex-5-ynyloxy)-2,2′:6′,2″-terpyridine: structural diversity arising from weak intermolecular interactions in the solid state

Edwin C. Constable,*a   Catherine E. Housecroft,*a   Markus Neuburger,a   Silvia Schaffnera  and  Ellen J. Shardlowa  

* Corresponding authors

a Department of Chemistry, University of Basel, Spitalstrasse 51, 4056 Basel, Switzerland
E-mail: catherine.housecroft@unibas.ch
Fax: +41 61 267 1018
Tel: +41 61 267 1001

Abstract

Changing the conditions under which 4′-(hex-5-ynyloxy)-2,2′:6′,2″-terpyridine crystallises results in solvent-free crystals in which dimeric motifs supported by C[triple bond, length as m-dash]CH⋯Npyridine hydrogen-bonded interactions assemble into two different 3D solid state structures.

Graphical abstract: Polymorphs of 4′-(hex-5-ynyloxy)-2,2′:6′,2″-terpyridine: structural diversity arising from weak intermolecular interactions in the solid state

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Article information

DOI
https://doi.org/10.1039/B512066G
Article type
Paper
Submitted
25 Aug 2005
Accepted
10 Oct 2005
First published
17 Oct 2005

CrystEngComm, 2005,7, 599-602

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Polymorphs of 4′-(hex-5-ynyloxy)-2,2′:6′,2″-terpyridine: structural diversity arising from weak intermolecular interactions in the solid state

E. C. Constable, C. E. Housecroft, M. Neuburger, S. Schaffner and E. J. Shardlow, CrystEngComm, 2005, 7, 599 DOI: 10.1039/B512066G

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