Issue 93, 2005
From the journal:

CrystEngComm

Carbonyl complexes of Rh(i) and Ir(i) and P-donor ligands as useful “building blocks” for the self-assembly of new organometallic polymers

Giulia Peli,*a   Silvia Rizzato,b   Simona Cassese,a   Luigi Garlaschellia  and  Mario Manasseroa  

* Corresponding authors

a Dipartimento di Chimica Inorganica, Metallorganica e Analitica, Via Venezian 21, 20133 Milano
E-mail: giulia.peli@unimi.it

b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Via Venezian 21, 20133 Milano

Abstract

We report here on three new 1-D polymeric species, obtained by self-assembly of Rh(I) and Ir(I) complexes of general formula [M(CO)2Cl2]− (M = Rh, Ir) with bidentate phosphine ligands as 1,2-bis(diphenylphosphino)acetylene (dppa) and trans-1,2-bis(diphenylphosphino)ethene (dppethe).

Graphical abstract: Carbonyl complexes of Rh(i) and Ir(i) and P-donor ligands as useful “building blocks” for the self-assembly of new organometallic polymers

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Article information

DOI
https://doi.org/10.1039/B510531E
Article type
Communication
Submitted
25 Jul 2005
Accepted
25 Aug 2005
First published
01 Sep 2005

CrystEngComm, 2005,7, 575-577

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Carbonyl complexes of Rh(I) and Ir(I) and P-donor ligands as useful “building blocks” for the self-assembly of new organometallic polymers

G. Peli, S. Rizzato, S. Cassese, L. Garlaschelli and M. Manassero, CrystEngComm, 2005, 7, 575 DOI: 10.1039/B510531E

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