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Issue 41, 2005
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Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

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Abstract

Asymmetric allylic amination or oxidation can be achieved by reaction of an alkene with a peroxycarbamate catalysed by a chiral copper bis-oxazoline complex, and the reaction can be tuned to give either the amination or oxidation product by reagent choice.

Graphical abstract: Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

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Publication details

The article was received on 08 Jul 2005, accepted on 15 Sep 2005 and first published on 29 Sep 2005


Article type: Communication
DOI: 10.1039/B509678B
Chem. Commun., 2005, 5175-5177

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    Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

    J. S. Clark and C. Roche, Chem. Commun., 2005, 5175
    DOI: 10.1039/B509678B

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