Issue 41, 2005
From the journal:

Chemical Communications

Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions†

J. Stephen Clark*a  and  Caroline Rochea  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: j.s.clark@nottingham.ac.uk
Fax: +44 115 9513564
Tel: +44 115 9513542

Abstract

Asymmetric allylic amination or oxidation can be achieved by reaction of an alkene with a peroxycarbamate catalysed by a chiral copper bis-oxazoline complex, and the reaction can be tuned to give either the amination or oxidation product by reagent choice.

Graphical abstract: Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

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Article information

DOI
https://doi.org/10.1039/B509678B
Article type
Communication
Submitted
08 Jul 2005
Accepted
15 Sep 2005
First published
29 Sep 2005

Chem. Commun., 2005, 5175-5177

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Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

J. S. Clark and C. Roche, Chem. Commun., 2005, 5175 DOI: 10.1039/B509678B

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