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Issue 31, 2005
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Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin

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Abstract

A self-complementary tecton based on a zinc porphyrin core bearing two pyridines at the opposite meso positions leads to the formation of a 3-D coordination network in the crystalline phase which offers channels which are filled with solvent molecules; reversible exchange of the guest molecules has been proven to take place in a single-crystal-to-single-crystal type transformation demonstrating the robustness of the coordination framework.

Graphical abstract: Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin

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Publication details

The article was received on 08 Jun 2005, accepted on 27 Jun 2005 and first published on 08 Jul 2005


Article type: Communication
DOI: 10.1039/B508135C
Chem. Commun., 2005, 3906-3908

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    Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin

    E. Deiters, V. Bulach and M. W. Hosseini, Chem. Commun., 2005, 3906
    DOI: 10.1039/B508135C

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