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Issue 27, 2005
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Stereoselective γ-lactam synthesis viapalladium-catalysed intramolecular allylation

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Abstract

A novel route to the synthesis of 3-(tolylsulfonyl)-4,5-cis-disubstituted γ-lactams using a diastereoselective palladium-catalysed intramolecular allylation of amino acid-derived allylic carbonates has been developed.

Graphical abstract: Stereoselective γ-lactam synthesis via palladium-catalysed intramolecular allylation

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Article information


Submitted
07 Mar 2005
Accepted
11 May 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3439-3441
Article type
Communication

Stereoselective γ-lactam synthesis via palladium-catalysed intramolecular allylation

D. Craig, C. J. T. Hyland and S. E. Ward, Chem. Commun., 2005, 3439
DOI: 10.1039/B504731E

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