Issue 29, 2005
From the journal:

Chemical Communications

Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis†

Arjan W. Kleij,a   Martin Lutz,b   Anthony L. Spek,b   Piet W. N. M. van Leeuwena  and  Joost N. H. Reek*a  

* Corresponding authors

a Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, The Netherlands
E-mail: reek@science.uva.nl
Fax: +3120-5256422
Tel: +3120-5256437

b Department of Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, Utrecht, The Netherlands
Fax: +3130-2533940
Tel: +3130-2532538

Abstract

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)–salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

Graphical abstract: Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Article information

DOI
https://doi.org/10.1039/B503708E
Article type
Communication
Submitted
14 Mar 2005
Accepted
13 May 2005
First published
10 Jun 2005

Chem. Commun., 2005, 3661-3663

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Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

A. W. Kleij, M. Lutz, A. L. Spek, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2005, 3661 DOI: 10.1039/B503708E

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