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Issue 29, 2005

Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

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Abstract

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)–salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

Graphical abstract: Encapsulated transition metal catalysts comprising peripheral Zn(ii)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

Supplementary files

Article information


Submitted
14 Mar 2005
Accepted
13 May 2005
First published
10 Jun 2005

Chem. Commun., 2005, 3661-3663
Article type
Communication

Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

A. W. Kleij, M. Lutz, A. L. Spek, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2005, 3661 DOI: 10.1039/B503708E

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