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Issue 17, 2005
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Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand

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Abstract

Addition of an equal molar quantity of R (R = Me, SiMe3) to complex (Nacnac)Ti[double bond, length as m-dash]NAr(OTf) (Nacnac = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3) forms the imido alkyl (Nacnac)Ti[double bond, length as m-dash]NAr(R), which can be readily protonated to afford [(Nacnac)Ti[double bond, length as m-dash]NAr(L)]+ (L = THF, Et2O, η1-C6H5NMe2), or treated with B(C6F5)3 to afford the zwitterion (Nacnac)Ti[double bond, length as m-dash]NAr(μ-CH3)B(C6F5)3.

Graphical abstract: Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand

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Publication details

The article was received on 10 Jan 2005, accepted on 23 Feb 2005 and first published on 11 Mar 2005


Article type: Communication
DOI: 10.1039/B500350D
Chem. Commun., 2005, 2250-2252

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    Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand

    F. Basuli, R. L. Clark, B. C. Bailey, D. Brown, J. C. Huffman and D. J. Mindiola, Chem. Commun., 2005, 2250
    DOI: 10.1039/B500350D

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