Issue 17, 2005
From the journal:

Chemical Communications

Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand†

Falguni Basuli,a   Rodney L. Clark,a   Brad C. Bailey,a   Doug Brown,a   John C. Huffmana  and  Daniel J. Mindiola*a  

* Corresponding authors

a Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana, USA
E-mail: Mindiola@indiana.edu
Fax: +1-812-855-8300
Tel: +1-812-855-2399

Abstract

Addition of an equal molar quantity of R− (R = Me, SiMe3) to complex (Nacnac)Ti[double bond, length as m-dash]NAr(OTf) (Nacnac− = [ArNC(tBu)]2CH, Ar = 2,6-iPr2C6H3) forms the imido alkyl (Nacnac)Ti[double bond, length as m-dash]NAr(R), which can be readily protonated to afford [(Nacnac)Ti[double bond, length as m-dash]NAr(L)]+ (L = THF, Et2O, η1-C6H5NMe2), or treated with B(C6F5)3 to afford the zwitterion (Nacnac)Ti[double bond, length as m-dash]NAr(μ-CH3)B(C6F5)3.

Graphical abstract: Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand

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Article information

DOI
https://doi.org/10.1039/B500350D
Article type
Communication
Submitted
10 Jan 2005
Accepted
23 Feb 2005
First published
11 Mar 2005

Chem. Commun., 2005, 2250-2252

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Latent low-coordinate titanium imides supported by a sterically encumbering β-diketiminate ligand

F. Basuli, R. L. Clark, B. C. Bailey, D. Brown, J. C. Huffman and D. J. Mindiola, Chem. Commun., 2005, 2250 DOI: 10.1039/B500350D

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