Issue 1, 2005
From the journal:

Chemical Communications

Anion dependence of Ag(i) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

Brandi L. Schottel,a   John Bacsaa  and  Kim R. Dunbar*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, PO Box 30012, College Station, USA
E-mail: dunbar@chem.mail.tamu.edu
Fax: +1 (979) 845-7177
Tel: +1 (979) 845-5235

Abstract

The new compound [Ag2(bptz)3][AsF6]2, prepared from the reaction of bptz with Ag[AsF6] in CH3CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(I) ions with [AsF6]− anions located in the folds of the cation.

Graphical abstract: Anion dependence of Ag(i) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

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Article information

DOI
https://doi.org/10.1039/B410811F
Article type
Communication
Submitted
21 Jul 2004
Accepted
12 Oct 2004
First published
19 Nov 2004

Chem. Commun., 2005, 46-47

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Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2

B. L. Schottel, J. Bacsa and K. R. Dunbar, Chem. Commun., 2005, 46 DOI: 10.1039/B410811F

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