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Issue 37, 2005
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Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

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Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as −0.28 V vs. SCE.

Graphical abstract: Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

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Article information


Submitted
28 Jun 2005
Accepted
29 Jul 2005
First published
23 Aug 2005

Chem. Commun., 2005, 4723-4725
Article type
Communication

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

X. Hu, B. M. Cossairt, B. S. Brunschwig, N. S. Lewis and J. C. Peters, Chem. Commun., 2005, 4723 DOI: 10.1039/B509188H

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