Issue 6, 2005
From the journal:

Chemical Communications

Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [GeIIN2]4− ions

Zoltán A. Gála  and  Simon J. Clarke*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, Oxfordshire, UK
E-mail: simon.clarke@chem.ox.ac.uk
Fax: +44 1865 272690
Tel: +44 1865 272600

Abstract

The layered nitride Sr11Ge4N6 contains Ge4− Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [GeIIN2]4− ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and −4.

Graphical abstract: Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [GeIIN2]4− ions

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Article information

DOI
https://doi.org/10.1039/B413534B
Article type
Communication
Submitted
06 Sep 2004
Accepted
29 Sep 2004
First published
21 Dec 2004

Chem. Commun., 2005, 728-730

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Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [GeIIN2]4− ions

Z. A. Gál and S. J. Clarke, Chem. Commun., 2005, 728 DOI: 10.1039/B413534B

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