A new diamido-amine ligand based on three-carbon atom “arms”: synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH2CH2CH2NSiMe3)2

Thomas A. Lowes; Benjamin D. Ward; Robert A. Whannel; Stuart R. Dubberley; Philip Mountford

doi:10.1039/B412381F

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A new diamido-amine ligand based on three-carbon atom “arms”: synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH₂CH₂CH₂NSiMe₃)₂†

Thomas A. Lowes,^a Benjamin D. Ward,^a Robert A. Whannel,^a Stuart R. Dubberley^a and Philip Mountford*^a

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* Corresponding authors

^a Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
E-mail: philip.mountford@chem.ox.ac.uk

Abstract

Zirconium compounds of the new diamido-amine ligand MeN(CH₂CH₂CH₂NSiMe₃)₂ feature significantly different molecular structures and considerably improved olefin polymerisation characteristics in comparison with analogous compounds based on the two-carbon arm homologues.

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Article information

DOI: https://doi.org/10.1039/B412381F
Article type: Communication
Submitted: 11 Aug 2004
Accepted: 23 Sep 2004
First published: 25 Nov 2004

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Chem. Commun., 2005, 113-115

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A new diamido-amine ligand based on three-carbon atom “arms”: synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH₂CH₂CH₂NSiMe₃)₂

T. A. Lowes, B. D. Ward, R. A. Whannel, S. R. Dubberley and P. Mountford, Chem. Commun., 2005, 113 DOI: 10.1039/B412381F

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