Jump to main content
Jump to site search

Issue 3, 2004
Previous Article Next Article

Crystal chemistry, properties and synthesis of microporous silicates containing transition elements

Author affiliations

Abstract

The review surveys and generalises recent data on synthesis methods, physicochemical properties and crystal chemistry of silicate microporous materials containing transition elements (amphoterosilicates). The frameworks of these materials, unlike those of usual aluminosilicate zeolites, are built from tetrahedrally coordinated atoms along with atoms of various elements (Ti, Nb, Zr, Ta, Sn, W, Fe, Mn, Zn, etc.) with coordination numbers of 6 or 5. Many amphoterosilicates possess ion-exchange properties and can serve as catalysts for redox reactions, sorbents, etc. The structural diversity of synthetic and natural amphoterosilicates provides the basis for the preparation of microporous materials with different properties. The bibliography includes 195 references.

Back to tab navigation

Publication details

The article was received on 21 Feb 2003


Article type: Review Article
DOI: 10.1070/RC2004v073n03ABEH000825
Russ. Chem. Rev., 2004,73, 205-223

  •   Request permissions

    Crystal chemistry, properties and synthesis of microporous silicates containing transition elements

    N. V. Chukanov, I. V. Pekov and R. K. Rastsvetaeva, Russ. Chem. Rev., 2004, 73, 205
    DOI: 10.1070/RC2004v073n03ABEH000825

Search articles by author

Spotlight

Advertisements