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Issue 6, 2004
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A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions

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Abstract

A new and convenient procedure for synthesis of homoallylic alcohols in generally good to excellent yields has been developed. The bismuth-mediated Barbier-type allylation of aldehydes (aromatic, aliphatic, alicyclic and heterocyclic) with allyl bromide has been carried out smoothly in water in the presence of fluoride ions.

Graphical abstract: A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions

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Article information


Submitted
08 Jan 2004
Accepted
11 Feb 2004
First published
25 Feb 2004

Org. Biomol. Chem., 2004,2, 935-938
Article type
Paper

A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions

K. Smith, S. Lock, G. A. El-Hiti, M. Wada and N. Miyoshi, Org. Biomol. Chem., 2004, 2, 935
DOI: 10.1039/B400179F

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