Issue 3, 2004
From the journal:

Organic & Biomolecular Chemistry

Pseudo-C3-symmetric trisoxazolines as ligands in copper catalyzed enantioselective Diels–Alder reaction

Jian Zhoua  and  Yong Tang*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 354 Fenglin Lu, Shanghai 200032, China
E-mail: tangy@mail.sioc.ac.cn

Abstract

Air- and water-stable chiral catalyst trisoxazolines 4–6/Cu(ClO4)2·6H2O have been used in the Diels–Alder reaction of cyclopentadiene with acryloyl-2-oxazolidinones or ketoesters. The reaction is carried out in air and up to 82% ee was achieved.

Graphical abstract: Pseudo-C3-symmetric trisoxazolines as ligands in copper catalyzed enantioselective Diels–Alder reaction

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Article information

DOI
https://doi.org/10.1039/B313796A
Article type
Paper
Submitted
31 Oct 2003
Accepted
04 Dec 2003
First published
14 Jan 2004

Org. Biomol. Chem., 2004,2, 429-433

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Pseudo-C3-symmetric trisoxazolines as ligands in copper catalyzed enantioselective Diels–Alder reaction

J. Zhou and Y. Tang, Org. Biomol. Chem., 2004, 2, 429 DOI: 10.1039/B313796A

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