Issue 2, 2004
From the journal:

Organic & Biomolecular Chemistry

The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

Martin G. Banwell,*a   Daniel A. S. Becka  and  Jason A. Smith†*a  

* Corresponding authors

a Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia
E-mail: mgb@rsc.anu.edu.au

Abstract

A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.

Graphical abstract: The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

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Article information

DOI
https://doi.org/10.1039/B312552A
Article type
Communication
Submitted
10 Oct 2003
Accepted
01 Dec 2003
First published
08 Dec 2003

Org. Biomol. Chem., 2004,2, 157-159

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The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

M. G. Banwell, D. A. S. Beck and J. A. Smith, Org. Biomol. Chem., 2004, 2, 157 DOI: 10.1039/B312552A

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