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Issue 4, 2004
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Total synthesis of (+)-tanikolide via oxidative lactonization

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Abstract

(+)-Tanikolide has been synthesized in eight linear steps with a 31% overall yield. The key step in the synthesis utilizes a recently developed tandem oxidative cleavage–lactonization of a precursor alkenol to deliver the lactone moiety.

Graphical abstract: Total synthesis of (+)-tanikolide via oxidative lactonization

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Article information


Submitted
19 Sep 2003
Accepted
15 Dec 2003
First published
27 Jan 2004

Org. Biomol. Chem., 2004,2, 621-624
Article type
Paper

Total synthesis of (+)-tanikolide via oxidative lactonization

J. M. Schomaker and B. Borhan, Org. Biomol. Chem., 2004, 2, 621
DOI: 10.1039/B311432E

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