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Issue 6, 2004
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Spontaneous resolution in a family of [2]catenanes containing proton-ionisable 1H-1,2,4-triazole subunits

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Abstract

A new donor–acceptor [2]catenane incorporating one 3,5-bis(methylene)-1H-1,2,4-triazole unit and one 1,5-dioxynaphthalene unit in the macrocyclic polyether component undergoes spontaneous resolution upon crystallisation, providing evidence that the inclusion of this triazole unit in the neutral component favours the phenomenon.

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Article information


Submitted
19 Oct 2004

Mendeleev Commun., 2004,14, 233-235
Article type
Communication

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