Issue 2, 2004
From the journal:

Mendeleev Communications

Catalytic methoxycarbonylation of alkoxyallenes

Boris A. Trofimov,*a   Anastasiya G. Mal'kina,a   Ravilya N. Kudyakova,a   Ol'ga A. Tarasova,a   Valentina V. Nosyrevaa  and  Andrei V. Afonina  

* Corresponding authors

a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation, ul. Favorskogo, 1, Irkutsk, Russian Federation
E-mail: tba@irioch.irk.ru

Abstract

Methoxyallene reacts with carbon monoxide in the PdCl2–CuCl2–NaHCO3 (NaHCO3/NaOAc) system in MeOH to afford methyl 2-(dimethoxymethyl)acrylate and 2-chloro-3,3-dimethoxyprop-1-ene; the third product, 2-chloro-1-methoxy-2-propenyl acetate, appears when NaHCO3–NaOAc is used as a buffer component.

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Article information

DOI
https://doi.org/10.1070/MC2004v014n02ABEH001878
Article type
Communication
Submitted
17 Dec 2003

Mendeleev Commun., 2004,014, 61-63

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Catalytic methoxycarbonylation of alkoxyallenes

B. A. Trofimov, A. G. Mal'kina, R. N. Kudyakova, O. A. Tarasova, V. V. Nosyreva and A. V. Afonin, Mendeleev Commun., 2004, 014, 61 DOI: 10.1070/MC2004v014n02ABEH001878

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