Issue 15, 2004
From the journal:

Journal of Materials Chemistry

A novel family of layered double hydroxides—[MAl4(OH)12](NO3)2·xH2O (M = Co, Ni, Cu, Zn)†

Andrew M. Fogg,‡*a   Gareth R. Williams,b   Ryan Chestera  and  Dermot O'Hare*b  

* Corresponding authors

a A.J. Parker Cooperative Research Centre for Hydrometallurgy, School of Applied Chemistry, Curtin University of Technology, P.O. Box U 1987, Perth 6845, Australia
E-mail: afogg@liverpool.ac.uk

b Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: dermot.ohare@chem.ox.ac.uk
Fax: 01865 285131
Tel: 01865 285130

Abstract

A class of layered double hydroxides with the layer composition [MAl4(OH)12](NO3)2·xH2O, where M = Zn, Cu, Ni and Co, has been synthesised for the first time and its anion exchange chemistry explored. These materials are related to the minerals chalcoalumite, mbobomkulite and nickelalumite (see M. Fleischer, R. G. Burns, L. J. Cabri, C. A. Francis and A. Pabst, Am. Miner., 1982, 67, 413).

Graphical abstract: A novel family of layered double hydroxides—[MAl4(OH)12](NO3)2·xH2O (M = Co, Ni, Cu, Zn)

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Article information

DOI
https://doi.org/10.1039/B409027F
Article type
Communication
Submitted
14 Jun 2004
Accepted
25 Jun 2004
First published
05 Jul 2004

J. Mater. Chem., 2004,14, 2369-2371

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A novel family of layered double hydroxides—[MAl4(OH)12](NO3)2·xH2O (M = Co, Ni, Cu, Zn)

A. M. Fogg, G. R. Williams, R. Chester and D. O'Hare, J. Mater. Chem., 2004, 14, 2369 DOI: 10.1039/B409027F

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