(EDT-TTF-I2)2PbI3·H2O: an ambient pressure metal with a β′ donor slab topology

Thomas Devic; Enric Canadell; Pascale Auban-Senzier; Patrick Batail

doi:10.1039/B312493B

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(EDT-TTF-I₂)₂PbI₃·H₂O: an ambient pressure metal with a β′ donor slab topology†

Thomas Devic,^a Enric Canadell,^b Pascale Auban-Senzier^c and Patrick Batail*^a

Author affiliations

* Corresponding authors

^a Laboratoire Chimie Inorganique, Matériaux et Interfaces, FRE 2447 CNRS-Université d'Angers, 2, Boulevard Lavoisier, Angers, France
E-mail: patrick.batail@univ-angers.fr

^b Institut de Ciència de Materials de Barcelona - CSIC, Campus de la U.A.B., Bellaterra, Spain

^c Laboratoire de Physique des Solides, UMR 8502 CNRS-Université de Paris-Sud, Orsay, France

Abstract

Water molecules are interspersed within ribbons of face-sharing [PbI_6/2⁻]_∞ octahedra within the title hybrid phase in which the stacks of organic radical cations are less strongly dimerised and interact more with each other than is usually the case in β′ phases to achieve metallic conductivity at ambient pressure.

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Article information

DOI: https://doi.org/10.1039/B312493B
Article type: Communication
Submitted: 07 Oct 2003
Accepted: 27 Nov 2003
First published: 12 Dec 2003

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J. Mater. Chem., 2004,14, 135-137

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(EDT-TTF-I₂)₂PbI₃·H₂O: an ambient pressure metal with a β′ donor slab topology

T. Devic, E. Canadell, P. Auban-Senzier and P. Batail, J. Mater. Chem., 2004, 14, 135 DOI: 10.1039/B312493B

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Journal of Materials Chemistry