Issue 10, 2004
From the journal:

Green Chemistry

Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen

Takayoshi Hara,a   Kohsuke Mori,a   Michitaka Oshiba,a   Tomoo Mizugaki,a   Kohki Ebitania  and  Kiyotomi Kaneda*a  

* Corresponding authors

a Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: kaneda@cheng.es.osaka-u.ac.jp
Fax: +81-6-6850-6260
Tel: +81-6-6850-6260

Abstract

A hydroxyapatite-supported Pd nanocluster (PdHAP) efficiently catalysed the dehalogenation of various organic halides in the presence of atmospheric molecular hydrogen; chlorobenzene gave benzene in an excellent TON of 10 000 for 10 h. Moreover, the dehalogenation of halophenols in aqueous conditions was also achieved.

Graphical abstract: Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen

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Article information

DOI
https://doi.org/10.1039/B408185D
Article type
Paper
Submitted
01 Jun 2004
Accepted
01 Jul 2004
First published
24 Sep 2004

Green Chem., 2004,6, 507-509

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Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen

T. Hara, K. Mori, M. Oshiba, T. Mizugaki, K. Ebitani and K. Kaneda, Green Chem., 2004, 6, 507 DOI: 10.1039/B408185D

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