Novel solid networks containing Sn–H as a greener replacement for soluble alkyl Sn–H reagents in radical assisted organic synthesis†
Abstract
DiGrignard reagents of the form XMg(CH2)nMgX, where X = Br or I and n
= 6, 8, 10 or 12, were allowed to react with PhSnCl3 to produce highly cross-linked Ph–Sn polymeric networks. The Sn–H moiety was incorporated into these insoluble network