Issue 24, 2004
From the journal:

Dalton Transactions

A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes

Carsten Schaefer,a   Rolf Gleiter*a  and  Frank Romingera  

* Corresponding authors

a Organisch-Chemisches Institut, Universität Heidelberg, INF 270, Heidelberg, Germany
E-mail: rolf.gleiter@urz.uni-heidelberg.de
Fax: +49 (6221) 544205
Tel: +49 (6221) 548400

Abstract

Sterically hindered CpCo stabilized cyclobutadiene complexes 4 were oxidized by ceric ammonium nitrate to yield the dinitratocobalt complexes 5. The thermolysis of 5a and the reaction of 5a with tert-butyl isocyanide as well as NaBH4 is reported.

Graphical abstract: A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes

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DOI
https://doi.org/10.1039/B412167H
Article type
Paper
Submitted
06 Aug 2004
Accepted
15 Oct 2004
First published
09 Nov 2004

Dalton Trans., 2004, 4146-4151

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A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes

C. Schaefer, R. Gleiter and F. Rominger, Dalton Trans., 2004, 4146 DOI: 10.1039/B412167H

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