Synthesis, crystal structures and magnetic properties of single and double cyanide-bridged bimetallic Fe2IIICuII zigzag chains†
Abstract
The bimetallic complexes [{FeIII(phen)(CN)4}2CuII(H2O)2]·4H2O (1), [{FeIII(phen)(CN)4}2CuII]·H2O (2) and [{FeIII(bipy)(CN)4}2CuII]·2H2O (3) and [{FeIII(bipy)(CN)4}2CuII(H2O)2]·4H2O (4)
(phen =