Issue 18, 2004
From the journal:

Dalton Transactions

Synthesis, structure and magnetism of a novel carboxylate bridged manganese(ii) sheet structure containing the first unsupported aqua bridge

Jeremy C. Goodwin,a   Daniel J. Priceb  and  Sarah L. Heath*a  

* Corresponding authors

a Department of Chemistry, University of Manchester, Oxford Road, Manchester, UK
E-mail: sarah.l.heath@man.ac.uk

b Department of Chemistry, University of Glasgow, University Avenue, Glasgow, Scotland, UK
E-mail: danielp@chem.gla.ac.uk

Abstract

The structural characterisation of a 2D sheet complex {[Mn2(Hetheidi)2(μ-H2O)(H2O)]·3H2O}n1 [Hetheidi = DL-N-(1-hydroxymethylpropyl)iminodiacetic acid] assembled from the tetradentate ligand Hetheidi and MnCl2 reveals the presence of rare unsupported μ-aqua bridges and novel hydrogen-bonded water channels, which bind the sheets together.

Graphical abstract: Synthesis, structure and magnetism of a novel carboxylate bridged manganese(ii) sheet structure containing the first unsupported aqua bridge

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Article information

DOI
https://doi.org/10.1039/B407495E
Article type
Communication
Submitted
18 May 2004
Accepted
02 Aug 2004
First published
20 Aug 2004

Dalton Trans., 2004, 2833-2835

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Synthesis, structure and magnetism of a novel carboxylate bridged manganese(II) sheet structure containing the first unsupported aqua bridge

J. C. Goodwin, D. J. Price and S. L. Heath, Dalton Trans., 2004, 2833 DOI: 10.1039/B407495E

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